By D. L. Kepert, K. Vrieze
Compounds of the Transition components concerning Metal-Metal Bonds bargains with compounds of the transition components concerning metal-metal bonds, with specific emphasis on metal-metal bonds in coordination compounds and organometallic complexes, halides, and oxides. components that impact the formation, balance, and homes of such compounds, in addition to their software in numerous fields of chemistry and physics, are mentioned.
This ebook is split into 4 sections and starts with a class of metal-metal bonds and a few of the actual and chemical equipment used to review them, together with X-ray crystallography, magnetic susceptibility and electron spin resonance, nuclear spin resonance, Mössbauer measurements, infrared and Raman spectroscopy, noticeable and ultraviolet spectroscopy, mass spectrometry, electric conductivity, electrochemical tools, and chemical reactivity. elements influencing the power of metal-metal bonds in metals and compounds also are tested. the remainder sections take care of metal-metal bonds in coordination compounds and organometallic complexes, halides, and oxides.
This monograph should be an invaluable source for inorganic chemists.
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Extra resources for Compounds of the Transition Elements Involving Metal–Metal Bonds
Oxford University Press (1961). 230 TRANSITION METAL-METAL BONDS: D. L. KEPERT AND K. VRIEZE the C O group is more extensive than for a C O group bonded to one metal atom and that more electronic charge is transferred from the metal atom. In Table 9 the known metal-metal bonded carbonyls and anions are listed, while the metal carbonyl hydrides are given in Table 10. TABLE 10. METAL-METAL BONDED CARBONYL HYDRIDES v 1° row V Cr Μη Fe H 2Mn 2(CO) 9 HFe 2(CO)i H 2Fe 2(CO) 8 HFe 3(CO)r! H 2Fe 3(CO)n HFe 4(CO)7 3 H 2Fe 4(CO) 13 H 3Mn 3(CO)i 2 2° row Nb Ta Te H 3Tc 3(CO) 12 3° row Ta W Re HRe 3(CO)i4 H 3Re 3(CO)i 2 Ru Co Ni H 2Ni 2(CO) 6 HNi 4(CO>9 HCo 6(CO)7 5 HNi 5(CO)9 Rh Pd Ir Pt H t tRu 4(CO)i 2 n = 2,3 H 2Ru 4(CO)i 3 H 4Ru 4(CO), 2 Os H 2Os 3(CO)io H„Os 4(CO)i 2 (n>5) H 2Os 4(CO)i 3 H 4Os4(CO)i 2 HIr 4(CO)r!
L. Pauson and L. M. Venanzi, Organometallic Chemistry, p. 468. ACS Monograph, Ed. H. Zeiss, Reinhold Publ. (1960). " 3 J. W. Cable and R. K. Sheline, Chem. Revs. 56 (1962) 22. 228 TRANSITION METAL-METAL BONDS: D . L. KEPERT AND K. VRIEZE It is not possible to satisfactorily discuss the polarity in a metal-metal bond between two different metals with different electronegativity as in Hg[Co(CO)4]2, but it is possible to compare roughly two analogous compounds, for example Cd[Co(CO)4]2 and 5 Hg[Co(CO)4]2, provided that the bonding is similar.
Is different from 2 H n R u 4 ( C O ) i 2 by Jamieson et al™ . 200 w . F. Edgell, M. T. Yang, Β. J. Bulkin, R. Bayer and N. Koizumi, / . Am. Chem. Soc. 87 (1965) 3080, and references therein. 201 K. Farmery, M. Kilber, R. Greatrex and Ν. N. Greenwood, Chem. Communs. (1968) 593. 202 j . w . S. Jamieson, J. V. Kingston and G. Wilkinson, Chem. Communs. (1966) 569. 203 β. F. G. Johnson, R. D. Johnston, J. Lewis and B. H. Robinson, Chem. Communs. (1966) 851. 204 w . Fellman, D . K. Huggins and H. D .
Compounds of the Transition Elements Involving Metal–Metal Bonds by D. L. Kepert, K. Vrieze