Catalysis in Ionic Liquids: From Catalyst Synthesis to by Chris Hardacre, Vasile Parvulescu, James J Spivey, Robin D PDF

By Chris Hardacre, Vasile Parvulescu, James J Spivey, Robin D Rogers

ISBN-10: 1849736030

ISBN-13: 9781849736039

Although ionic beverages have in basic terms been studied intensive over the past a long time, the sphere is now maturing to any such measure that the point of interest is on better scale purposes to be used in genuine tactics similar to catalysis. present details is scattered around the literature and Catalysis in Ionic beverages offers a serious research of the study released so far on ionic solvents in all components of the catalytic technology. The booklet covers either catalyst synthesis utilizing ionic beverages as solvents and eco-friendly syntheses utilizing either ionic drinks in addition to combos of ionic drinks and carbon dioxide (as a subcritical and supercritical liquid), together with enzymatic, homogeneous, and heterogeneous catalysis, electrocatalysis and organocatalysis. in addition to the catalysis group, the publication can also be of curiosity to postgraduates, postdoctoral employees and researchers in academia and operating in natural synthesis, new fabrics synthesis, renewable assets of strength and electrochemistry. Written by means of major specialists within the box, this can be the reference resource to discover approximately catalysis in ionic liquids.

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C. De Long and R. A. Mantz, J. Am. Chem. , 2004, 126, 14350. 29. H. Xie, S. Li and S. , 2005, 7, 606. 30. N. Sun, M. Rahman, Y. Qin, M. L. Maxim, H. Rodrı´guez and R. D. , 2009, 11, 646. 31. D. A. Fort, R. C. Remsing, R. P. Swatloski, P. Moyna, G. Moyna and R. D. , 2007, 9, 63. 32. W. Li, N. Sun, B. Stoner, X. Jiang, X. Lu and R. D. , 2011, 13, 2038. 33. Z. Wang, L. Li, K. Xiao and J. Wu, Bioresour. , 2009, 100, 1687. 34. Y. Cao, H. Li, Y. Zhang, J. Zhang and J. He, J. Appl. Polym. , 2010, 116, 547.

View Online 38 Chapter 2 OH 12/04/2014 12:03:38. 17 CaLB catalyzed acylation of sucrose in tert-butanol. Obviously, such a slow reaction is not attractive for large scale production and, notwithstanding the substantial research effort devoted to this topic, a commercially viable process for the biocatalytic acylation of sucrose with fatty acid esters has not been forthcoming. Therefore, attention has turned to the design of ILs that can function as reaction media for the synthesis of sugar fatty acid esters in general and sucrose fatty acid esters in particular.

C. Bruce, Tetrahedron, 2004, 60, 561. 61. D. Das, A. Dasgupta and P. K. , 2007, 48, 5635. View Online 12/04/2014 12:03:38. 1039/9781849737210-00020 42 Chapter 2 62. A. R. Toral, A. P. De los Rios, F. J. Hernandez, M. H. A. Janssen, R. Schoevaart, F. Van Rantwijk and R. A. Sheldon, Enzyme Microb. , 2007, 40, 1095. 63. C. Vafiadi, E. Topakas, V. R. Nahmias, C. B. Faulds and P. Christakopoulos, J. , 2009, 139, 124. 64. S. Shah and M. N. Gupta, Bioorg. Med. Chem. , 2007, 17, 921. 65. P. Hara, U. Hanefeld and L.

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Catalysis in Ionic Liquids: From Catalyst Synthesis to Application by Chris Hardacre, Vasile Parvulescu, James J Spivey, Robin D Rogers

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