Calixarenes and Beyond - download pdf or read online

By Placido Neri, Jonathan L. Sessler, Mei-Xiang Wang

ISBN-10: 3319318659

ISBN-13: 9783319318653

ISBN-10: 3319318675

ISBN-13: 9783319318677

Contributions that includes the chemistry and purposes of a family members of macrocyclic compounds jointly often called 'calixarenes' are awarded during this edited quantity. The arsenal of constructions in keeping with calixarenes presents instruments that are potent in different components of supramolecular chemistry. The Editors have compiled a well timed quantity which incorporates modern, excessive calibre contributions from a lot of overseas authors. A wide point of view at the development and way forward for calixarene chemistry is gifted. aimed toward scholars and researchers energetic in Supramolecular Chemistry.

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104. ; B€ohmer, V. Supramol. Chem. 2010, 22, 717–725. 105. ; Vysotsky, M. ; Bohmer, V. Chem. Commun. 2003, 1124–1125. 106. ; Zheng, Y. S. Curr. Org. Chem. 2012, 16, 483–506. 107. ; Reinhoudt, D. N. Supramol. Chem. 2007, 19, 95–106. 108. Prins, L. ; Reinhoudt, D. N. Nature 1999, 398, 498–502. 109. ; Reinhoudt, D. ; Shinkai, S. Angew. Chem. Int. Ed. 2002, 41, 1924–1929. 110. ; Reinhoudt, D. ; Shinkai, S. J. Am. Chem. Soc. 2002, 124, 14631–14641. 1 Foreword One of the main advantages of the chemistry of calixarenes is the fact that they can be, with only few limitations, easily derivatised by numerous functional groups.

Zhang, C. Org. Lett. 2004, 6, 1189–1192. 44. Liu, X. ; Zheng, Y. S. Tetrahedron Lett. 2006, 47, 6357–6360. 45. ; Sirit, A. Tetrahedron: Asymmetry 2008, 19, 618–623. 46. ; Jabin, I. Tetrahedron: Asymmetry 2005, 16, 3767–3771. 47. ; Jabin, I. J. Org. Chem. 2005, 70, 10552–10560. 48. Wezenberg, S. ; Kleij, A. W. Adv. Synth. Catal. 2010, 352, 85–91. 49. Amato, M. ; Ballistreri, F. ; Tomaselli, G. ; Toscano, R. ; Williams, D. J. Eur. J. Org. Chem. 2005, 3562–3570. 50. ; Ungaro, R. J. Org. Chem. 1997, 62, 8654–8659.

However, the complexation process is hedged by a high kinetic barrier. Therefore, complexation of fullerenes can only be realized at the step of capsule formation (during chemical reaction) or, by pushing fullerenes into capsules by mechanochemical methods. Interestingly, the chiral cavity has a profound effect on the 13C NMR spectrum of fullerene C70. Enantiotopic carbon atoms became diastereotopic in the chiral environment and therefore exhibited different chemical shifts. 2 Chiral Calixarenes and Resorcinarenes 21 Fig.

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Calixarenes and Beyond by Placido Neri, Jonathan L. Sessler, Mei-Xiang Wang

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