Boron Science: New Technologies and Applications - download pdf or read online

By Narayan S. Hosmane

ISBN-10: 1283350114

ISBN-13: 9781283350112

Boron has made an important impression in our lives via its quiet use in fertilizers, fungicides, soaps, detergents, and heat-resistant glassware. Boron technology: New applied sciences and Applications addresses the purposes of boron in chemistry, undefined, medication, and pharmacology via explaining its position in difficulties akin to catalysis and hydroboration in addition to its use in superconductors, fabrics, magnetic/nonmagnetic nanoparticles, and clinical functions together with melanoma therapy.

Illustrating the sensible versatility of boron, the 29 chapters are divided into seven significant sections:

  • Boron for dwelling: Medicine
  • Boron for dwelling: health and wellbeing and Nutrition
  • Boron for dwelling: Radioisotope
  • Boron for residing: Boron Neutron seize Therapy
  • Boron for Electronics: Optoelectronics
  • Boron for power: power garage, area, and different Applications
  • Boron for Chemistry and Catalysis: Catalysis and natural Transformations

More than simply an up to date compilation of development within the utilized technological know-how of boron, this publication is a tribute to the legions of staff who've spent years engaging in groundbreaking experiences. The ebook celebrates those scientists and their protégés, who jointly reworked boron technological know-how into the intriguing and growing to be zone it truly is this day.

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Extra resources for Boron Science: New Technologies and Applications

Sample text

Adapted from Lesnikowski, Z. ; Schinazi, R. F. 1993. J. Org. Chem. ) Carbaboranyl bisglycophosphonates were synthesized according to the phosphoramidite method from meta- or para-carbaboranyl bisphosphonite and isopropylidene-protected galactose (59) with benzimidazolium triflate (BIT) as the promoter. Due to strong P⋅⋅⋅P interactions in ortho-carborane derivatives, the synthesis of the respective carbaboranyl bisglycophosphonates was unsuccessful. Synthesis of disodium salts 62 and 63 starts from meta-carbaboranyl bisphosphonite 58, which acts as a phosphoramidite analog.

I. Bregadze, I. B. Sivaev, S. A. Glazun, Polyhedral boron compounds as potential diagnostic and therapeutic antitumor agents, Anti-Cancer Agents Med. , 2006, 6, 75. 12. S. Sjöberg, J. Carlsson, H. Ghaneolhosseini, L. Gedda, T. Hartman, J. Malmquist, C. Naeslund, P. Olsson, W. Tjarks, Chemistry and biology of some low molecular weight boron compounds for boron neutron capture therapy, J. , 1997, 33, 41–52. 18 Boron Science 13. J. F. Valliant, K. J. Guenther, A. S. King, P. Morel, P. Schaffer, O.

These advantages were first exploited for modification of amino acids and peptides. l-Ortho-carboranylalanine and several other carborane-modified amino acids were synthesized in the late seventies. The lipophilicity of l-ortho-carboranylalanine assigned by partition coefficient measurement was much higher than that of the parent l-phenylalanine and higher than that of another lipophilic phenylalanine analog, l-adamantylalanine. Subsequently, several analogs of biologically active peptides, such as enkephalin, angiotensin, bradykinin, substance P, and insect neuropeptide pyrokinin in which the residue Phe and/or Tyr was replaced with carborane-bearing amino acid analog, have been synthesized.

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Boron Science: New Technologies and Applications by Narayan S. Hosmane

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