By W. Hüttner, J. Demaison, J. Vogt (auth.), W. Hüttner (eds.)
Volume II/29 "Molecular Constants generally from Microwave, Molecular Beam, and Sub-Doppler Laser Spectroscopy" is deliberate to seem as a chain A, B, C and D1, D2, D3 for the diamagnetic, and E for the paramagnetic linear and polyatomic species, respectively. Like within the preseding volumes II/24 and II/19, that have seemed within the years round 1999 and 1992, respectively, the diamagnetic ingredients are prepared within the demeanour advised through Hill ("Hill's system", 1900), which means a nearly strict alphabetical order. The ionic species are integrated within the alphabetical association of the impartial ones in every one desk. the data is grouped otherwise compared to the former volumes. All proper houses of a molecule and the corresponding parameters are available targeted less than its sum formulation in quantity II/29. this diminishes the necessity of turning pages simply because rotational and similar constants, dipole moments, obstacles to inner rotation, hyperfine coupling parameters, or Zeeman facts have been hitherto indexed in numerous tables. the current subvolume II/29D2 includes information for uneven best molecules.
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Additional info for Asymmetric Top Molecules. Part 2
18) (K = Ka for nearly prolate, K = Kc for nearly oblate). 2 Magnetic-interaction constants, defining equations The spectroscopic determination of the spin-rotation-, spin-spin-, and nuclear-shielding parameters of diamagnetic molecules compiled here requires a resolving power of the order of l…10 kHz. This can be achieved with the MWFT method or with molecular-beam techniques in current use so that the reader will find several molecules in the tables below where some of the pertinent parameters have been determined.
Ref. p. 21 Note that authors sometimes use the notation Mk instead of Ck for the spin-rotation tensor. It is appropriate to refer these quantities to the molecular principal-axis system (a, b, c). In this way, the tensor k kl k components Cgg c , Dgg c , g gg c , [ gg c and V gg c become uniquely defined molecular properties (g, gƍ = a, b, c). However, only the diagonal tensor components are useful in analyzing hfs spectra as non-diagonal terms, g z gƍ do not enter matrix elements diagonal in J, and higher-than-first-order rotational perturbations of H are barely observable.
Pol. A 104 (2003) 415. : J. Chem. Phys. 119 (2003) 7749. 1007/978-3-642-10400-8_3 © Spr inger 2011 32 256 C3HHeN 2-Propynenitrile - helium (1/1) 256 C3HHeN 2-Propynenitrile - helium (1/1) Constants: (A, B, C), χgg(14N, D) For definitions, see Introduction H C C C N He Structural parameters: See [05Top] (T-shaped complex). : J. Chem. Phys. 123 (2005) 064303. : 4452-08-8 C N C O Structural parameters: See [04Hah]. 381(17) Other centrifugal distortion constants fixed to the values of the parent isotopologue.
Asymmetric Top Molecules. Part 2 by W. Hüttner, J. Demaison, J. Vogt (auth.), W. Hüttner (eds.)