Download e-book for kindle: Alkene Metathesis in Organic Synthesis (Topics in by Alois Fuerstner

By Alois Fuerstner

ISBN-10: 3540642544

ISBN-13: 9783540642541

The large growth in olefin metathesis completed over the past decade can not often be overvalued. as a result of the improvement of a brand new iteration of good outlined and high-performance organometallic catalysts, this response is quickly evolving into some of the most flexible instruments for complicated natural chemistry, normal product synthesis, tremendous chemical creation and polymer sciences. Written by means of a few of the best specialists during this box, this monograph intends to familiarize the reader with the main interesting advancements and frontiers during this flourishing box of chemistry study.

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Extra info for Alkene Metathesis in Organic Synthesis (Topics in Organometallic Chemistry) (Vol 1)

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The alternative path in which both phosphine ligands remain attached to the central metal, though operative, is much less efficient. 42 A. Fürstner Scheme 5. Scheme 6. The olefin binding site is presumed to be cis to the carbene and trans to one of the chlorides. Subsequent dissociation of a phosphine paves the way for the formation of a 14-electron metallacycle G which upon cycloreversion generates a productive intermediate [11]. The metallacycle formation is the rate determining step. The observed reactivity pattern of the pre-catalyst outlined above and the kinetic data presently available support this mechanistic picture.

67. 68. 69. 70. 71. 72. 73. 74. 75. 76. 77. 78. 79. 80. 81. Richard R. Schrock Peters JU, Blechert S (1997) Chem Commun 1983 Feldman J, Schrock RR (1991) Prog Inorg Chem 39:1 Buhro WE, Chisholm MH (1987) Adv Organometal Chem 27:311 Breslow DS (1993) Progress in Polymer Science 18:1141 Streck R (1988) J Mol Catal 46:305 Nugent WA, Feldman J, Calabrese JC (1995) J Am Chem Soc 117:8992 Xu Z, Johannes CW, Houri AF, La DS, Cogan DA, Hofilena GE, Hoveyda AH (1997) J Am Chem Soc 119:10302 Parkin G, Bunel E, Burger BJ, Trimmer MS, van Asselt A, Bercaw JE (1987) J Molec Catal 41:21 Freundlich JS, Schrock RR, Davis WM (1996) J Am Chem Soc 118:3643 Freundlich JS, Schrock RR, Davis WM (1996) Organometallics 15:2777 Edwards DS, Biondi LV, Ziller JW, Churchill MR, Schrock RR (1983) Organometallics 2:1505 van der Schaff PA, Hafner A, Mühlebach A (1996) Angew Chem Int Ed Engl 35:1845 Johnson LK, Frey M, Ulibarri TA, Virgil SC, Grubbs RH, Ziller JW (1993) J Am Chem Soc 115:8167 Sharp PR, Schrock RR (1979) J Organometal Chem 171:43 Wengrovius JH, Schrock RR (1982) Organometallics 1:148 Binger P, Müller P, Benn R, Mynott R (1989) Angew Chem 101:647 Johnson LK, Grubbs RH, Ziller JW (1993) J Am Chem Soc 115:8130 de la Mata FJ, Grubbs RH (1996) Organometallics 15:577 de la Mata FJ (1996) J Organomet Chem 525:183 Wu Z, Wheeler DR, Grubbs RH (1992) J Am Chem Soc 114:146 Murdzek JS, Schrock RR (1988) In: (ed) Carbyne complexes.

68. 69. 70. 71. 72. 73. 74. 75. 76. 77. 78. 79. 80. 81. Richard R. Schrock Peters JU, Blechert S (1997) Chem Commun 1983 Feldman J, Schrock RR (1991) Prog Inorg Chem 39:1 Buhro WE, Chisholm MH (1987) Adv Organometal Chem 27:311 Breslow DS (1993) Progress in Polymer Science 18:1141 Streck R (1988) J Mol Catal 46:305 Nugent WA, Feldman J, Calabrese JC (1995) J Am Chem Soc 117:8992 Xu Z, Johannes CW, Houri AF, La DS, Cogan DA, Hofilena GE, Hoveyda AH (1997) J Am Chem Soc 119:10302 Parkin G, Bunel E, Burger BJ, Trimmer MS, van Asselt A, Bercaw JE (1987) J Molec Catal 41:21 Freundlich JS, Schrock RR, Davis WM (1996) J Am Chem Soc 118:3643 Freundlich JS, Schrock RR, Davis WM (1996) Organometallics 15:2777 Edwards DS, Biondi LV, Ziller JW, Churchill MR, Schrock RR (1983) Organometallics 2:1505 van der Schaff PA, Hafner A, Mühlebach A (1996) Angew Chem Int Ed Engl 35:1845 Johnson LK, Frey M, Ulibarri TA, Virgil SC, Grubbs RH, Ziller JW (1993) J Am Chem Soc 115:8167 Sharp PR, Schrock RR (1979) J Organometal Chem 171:43 Wengrovius JH, Schrock RR (1982) Organometallics 1:148 Binger P, Müller P, Benn R, Mynott R (1989) Angew Chem 101:647 Johnson LK, Grubbs RH, Ziller JW (1993) J Am Chem Soc 115:8130 de la Mata FJ, Grubbs RH (1996) Organometallics 15:577 de la Mata FJ (1996) J Organomet Chem 525:183 Wu Z, Wheeler DR, Grubbs RH (1992) J Am Chem Soc 114:146 Murdzek JS, Schrock RR (1988) In: (ed) Carbyne complexes.

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Alkene Metathesis in Organic Synthesis (Topics in Organometallic Chemistry) (Vol 1) by Alois Fuerstner


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