Read e-book online Advanced Inorganic Chemistry, Third Edition PDF

By F. Albert, And Geoffrey Wilkinson, Cotton

ISBN-10: 0471175609

ISBN-13: 9780471175605

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Quantity II/25 is a supplemented and revised variation of the previous volumes II/7, II/15, II/21 and II/23 containing modern info on inorganic and natural polyatomic molecules. All experimental tools for the selection of quantitative structural information of loose molecules were thought of: microwave, infrared, Raman, digital and photoelectron spectroscopy in addition to electron diffraction.

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104. ; B€ohmer, V. Supramol. Chem. 2010, 22, 717–725. 105. ; Vysotsky, M. ; Bohmer, V. Chem. Commun. 2003, 1124–1125. 106. ; Zheng, Y. S. Curr. Org. Chem. 2012, 16, 483–506. 107. ; Reinhoudt, D. N. Supramol. Chem. 2007, 19, 95–106. 108. Prins, L. ; Reinhoudt, D. N. Nature 1999, 398, 498–502. 109. ; Reinhoudt, D. ; Shinkai, S. Angew. Chem. Int. Ed. 2002, 41, 1924–1929. 110. ; Reinhoudt, D. ; Shinkai, S. J. Am. Chem. Soc. 2002, 124, 14631–14641. 1 Foreword One of the main advantages of the chemistry of calixarenes is the fact that they can be, with only few limitations, easily derivatised by numerous functional groups.

Zhang, C. Org. Lett. 2004, 6, 1189–1192. 44. Liu, X. ; Zheng, Y. S. Tetrahedron Lett. 2006, 47, 6357–6360. 45. ; Sirit, A. Tetrahedron: Asymmetry 2008, 19, 618–623. 46. ; Jabin, I. Tetrahedron: Asymmetry 2005, 16, 3767–3771. 47. ; Jabin, I. J. Org. Chem. 2005, 70, 10552–10560. 48. Wezenberg, S. ; Kleij, A. W. Adv. Synth. Catal. 2010, 352, 85–91. 49. Amato, M. ; Ballistreri, F. ; Tomaselli, G. ; Toscano, R. ; Williams, D. J. Eur. J. Org. Chem. 2005, 3562–3570. 50. ; Ungaro, R. J. Org. Chem. 1997, 62, 8654–8659.

However, the complexation process is hedged by a high kinetic barrier. Therefore, complexation of fullerenes can only be realized at the step of capsule formation (during chemical reaction) or, by pushing fullerenes into capsules by mechanochemical methods. Interestingly, the chiral cavity has a profound effect on the 13C NMR spectrum of fullerene C70. Enantiotopic carbon atoms became diastereotopic in the chiral environment and therefore exhibited different chemical shifts. 2 Chiral Calixarenes and Resorcinarenes 21 Fig.

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Advanced Inorganic Chemistry, Third Edition by F. Albert, And Geoffrey Wilkinson, Cotton

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